Beilstein J. Org. Chem.2020,16, 159–167, doi:10.3762/bjoc.16.18
reactions, a mechanism is proposed in which the key steps are supported by quantum chemical calculations.
Keywords: benzylamines; carbamothioates; density functional theory; intrinsicreactioncoordinateanalysis; isocyanides; sodium hydride; xanthate esters; Introduction
Carbamothioates (thiocarbamates
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Graphical Abstract
Scheme 1:
Synthesis of carbamothioates from xanthate esters and benzyl isocyanides.